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拡散係数

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Molecular diffusion from a microscopic and macroscopic point of view. Initially, there are solute molecules on the left side of a barrier (purple line) and none on the right. The barrier is removed, and the solute diffuses to fill the whole container. Top: A single molecule moves around randomly. Middle: With more molecules, there is a clear trend where the solute fills the container more and more uniformly. Bottom: With an enormous number of solute molecules, randomness becomes undetectable: The solute appears to move smoothly and systematically from high-concentration areas to low-concentration areas. This smooth flow is described by Fick's laws.

フィックの拡散法則物質移動のメカニズムと科学的応用

フィックの法則拡散係数濃度勾配ブラウン運動
A basic diagram of a fluorescence correlation spectroscopy instrument.

蛍光相関分光法(FCS)による分子ダイナミクスの精密解析

蛍光相関分光法FCSブラウン運動拡散係数
The temperature of the ideal gas is proportional to the average kinetic energy of its particles. The size of helium atoms relative to their spacing is shown to scale under 1,950 atmospheres of pressure. The atoms have an average speed relative to their size slowed down here two trillion fold from that at room temperature.

気体分子運動論ミクロな粒子の動きから解き明かす熱力学の正体

気体分子運動論理想気体熱力学マックスウェル・ボルツマン分布